News Flash  

Sep. 2016: Second Workshop on Hierarchical Materials in Erlangen: RV with invited lecture on transport properties of hierarchical porous solids.

Sep. 2015: IUPAC has established the task group "Diffusion in nanoporous solids" involving us as the active members.

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Sep. 2015Our work on diffusion in hollow core-shell nanoparticles just appeared in Langmuir.

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Seminars  

R. Valiullin: Mesoporous materials -- Perspectives revealed by fluids confined in their pore spaces
Mo, 27.06.2016, 17:15–18:00
Universität Hamburg, Fachbereich Chemie, Martin-Luther-King-Platz 6, Hörsaal C

October 21-23, 2015
R. Valiullin: NMR Cryoporometry: From fundamentals to application
Workshop: Methods of Porosimetry and Applications (HZDR Dresden-Rossendorf)

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Publications

Diffusion NMR of Confined Systems

Fluid Transport in Porous Solids and Heterogeneous Materials

Edited by
Rustem Valiullin
Leipzig University, Leipzig, Germany

New Developments in NMR No. 9
Print ISBN: 978-1-78262-190-4

PDF eISBN: 978-1-78262-377-9
EPUB eISBN: 978-1-78262-970-2
ISSN: 2044-253X

© The Royal Society of Chemistry 2017

(RSC Publishing) (Amazon)

With the increasing role of porous solids in conventional and newly emerging technologies, there is an urgent need for a deeper understanding of fluid behaviour confined to pore spaces of these materials especially with regard to their transport properties. From its early years, NMR has been recognized as a powerful experimental technique enabling direct access to this information. In the last two decades, the methodological development of different NMR techniques to assess dynamic properties of adsorbed ensembles has been progressed. This book will report on these recent advances and look at new broader applications in engineering and medicine. Having both academic and industrial relevance, this unique reference will be for specialists working in the research areas and for advanced graduate and postgraduate studies who want information on the versatility of diffusion NMR.

Front Matter     ♦    Preface      ♦     Content 


- NMR under Confinement: Roots in Retrospect
- Fundamentals of Diffusion Measurements using NMR
- From the Microstructure to Diffusion NMR, and Back
- Two-dimensional NMR of Diffusion and Relaxation
- Transport in Structured Media: Multidimensional PFG-NMR Applied to Diffusion and Flow Processes
- Real Time PGSE NMR Through Direct Acquisition of Averaged Propagators in the Time Domain Using Pulsed Second Order Magnetic Fields
- NMR Methods for Studying Microscopic Diffusion Anisotropy
- Beyond the Limits of Conventional Pulsed Gradient Spin Echo (PGSE) Diffusometry: Generalization of the Magnetization-grating Principle
- Probing Exchange and Diffusion in Confined Systems by 129Xe NMR Spectroscopy
- Diffusive Dynamics in Porous Materials as Probed by NMR Relaxation-based Techniques
- Industrial Applications of Magnetic Resonance Diffusion and Relaxation Time Measurements
- Confined Fluids: NMR Perspectives on Confinements and on Fluid Dynamics
- NMR and Complementary Approaches to Establishing Structure–Transport Relationships in Disordered Porous
- NMR Diffusometry for the Study of Energy-related Soft Materials
- Diffusion Magnetic Resonance Imaging in Brain Tissue
- Surface Effect Dominates Water Diffusion at Nanoscopic Length Scales Solids

  1. Measuring Mass Transport in Hierarchical Pore Systems
    Kärger, J., R. Valiullin, D. Enke, and R. Gläser in Mesoporous Zeolites: Preparation, Characterization and Application, J. Garcia-Martinez and K. Li, Editors. 2015, Wiley-VCH: Weinheim, p. 385-424.
  2. NMR Cryoporometry and Estimation of Pore Sizes in Mesoporous Silicon
    (Revised 2017)
    Valiullin, R. in Handbook of Porous Silicon, L. Canham, Editor. 2014, Springer International Publishing, pp. 439-447.
  3. Mesoporous Silicon
    (Revised 2017)
    Khokhlov, A. and R. Valiullin in Handbook of Porous Silicon, L. Canham, Editor. 2014, Springer International Publishing, pp. 115-127.
  4. Mesopore Diffusion Within Porous Silicon
    Kärger, J. and R. Valiullin in Handbook of Porous Silicon, L. Canham, Editor. 2014, Springer International Publishing, pp. 221-230.
  5. Diffusion in porous media  
    Kärger, J. and R. Valiullin in Encyclopedia of Magnetic Resonance, R. K. Harris, R. E. Wasylishen, Editors 2011, John Wiley: Chichester (DOI: 10.1002/9780470034590.emrstm0121.pub2)
  6. Anomalous molecular dynamics in confined spaces
    Valiullin, R. and J. Kärger in Anomalous Transport: Foundations and Applications, R. Klages, G. Radons, and I.M. Sokolov, Editors 2008, Wiley-VCH: Weinheim
  7. Diffusion in nanoporous materials
    Kärger, J., F. Stallmach, R. Valiullin, and S. Vasenkov in NMR Imaging in Chemical Engineering, S. Stapf and S. Han, Editors 2005, Wiley-VCH: Weinheim
 
  1. Water Transport in Periodic Mesoporous Organosilica Materials 
    Mietner, B.J., M. Fröba, and R. Valiullin, J. Phys. Chem. C, 122 (2018) 12673
  2. Ice nucleation in periodic arrays of spherical nanocages
    Mascotto, S., W. Janke, and R. Valiullin, J. Phys. Chem. C, 121 (2017) 23788
  3. Phase transitions in disordered mesoporous solids (open access)
    Schneider, D., D. Kondrashova, and R. Valiullin, Sci Rep, 7 (2017) 7216
  4. Structure-correlated diffusion anisotropy in nanoporous channel networks by Monte Carlo simulations and percolation theory
    Kondrashova, D., R. Valiullin, J. Kärger, and A. Bunde, The European Physical Journal B, 90 (2017) 136
  5. Scale-dependent diffusion anisotropy in nanoporous silicon (open access)
    Kondrashova, D., A. Lauerer, D. Mehlhorn, H. Jobic, A. Feldhoff, M. Thommes, D. Chakraborty, C. Gommes, J. Zecevic, P. de Jongh, A. Bunde, J. Kärger, and R. Valiullin, Sci Rep, 7 (2017) 40207
  6. Transport properties of hierarchical micro-mesoporous materials (open access)
    Schneider, D., D. Mehlhorn, P. Zeigermann, J. Kärger, and R. Valiullin, Chem. Soc. Rev., 45 (2016) 3439  
  7. Diffusion in complementary pore spaces
    Mehlhorn, D., D. Kondrashova, C. Küster, D. Enke, T. Emmerich, A. Bunde, R. Valiullin, and J. Kärger, Adsorption, 22 (2016) 879
  8. Field-Cycling Relaxometry as a Molecular Rheology Technique: Common Analysis of NMR, Shear Modulus and Dielectric Loss Data of Polymers vs Dendrimers
    Hofmann, M., C. Gainaru, B. Cetinkaya, R. Valiullin, N. Fatkullin, and E.A. Rössler, Macromolecules, 48 (2015) 7521
  9. Mesopore-Promoted Transport in Microporous Materials
    Schneider, D., D. Kondrashova, R. Valiullin, A. Bunde, and J. Kärger, Chem. Ing. Tech., 87 (2015) 1794
  10. Diffusion and Molecular Exchange in Hollow Core–Shell Silica Nanoparticles
    Pochert, A., D. Schneider, J. Haase, M. Linden, and R. Valiullin, Langmuir, 31 (2015) 10285
  11. Freezing and Melting Transitions under Mesoscalic Confinement: Application of the Kossel–Stranski Crystal-Growth Model
    Kondrashova, D. and R. Valiullin, J. Phys. Chem. C, 119 (2015) 4312
  12. Modeling the Influence of Side Stream and Ink Bottle Structures on Adsorption/Desorption Dynamics of Fluids in Long Pores
    Schneider, D., R. Valiullin, and P.A. Monson, Langmuir, 31 (2015) 188
  13. Micro-imaging of liquid-vapor phase transition in nano-channels
    Lauerer, A., P. Zeigermann, J. Lenzner, C. Chmelik, M. Thommes, R. Valiullin, and J. Kärger, Microporous Mesoporous Mat. 214 (2015) 143
  14. Driven diffusion in nanoscaled materials (open access)
    Albers, T., M. Bauer, C. von Borczyskowski, F. Gerlach, M. Heidernätsch, J. Kärger, D. Kondrashova, G. Radons, T. Schubert, A. Shakhov, D. Täuber, R. Valiullin, and P. Zeigermann, Diffusion Fundamentals, 23 (2015) 1
  15. Improving mass-transfer in controlled pore glasses as supports for the platinum-catalyzed aromatics hydrogenation
    Goepel, M., H. Kabir, C. Kuster, E. Saraci, P. Zeigermann, R. Valiullin, C. Chmelik, D. Enke, J. Karger, and R. Glaser, Catal. Sci. Technol. 5 (2015) 3137
  16. Diffusion properties of liquid crystal-based microemulsions
    Shakhov, A., J. Kärger, and R. Valiullin, Colloid Polym. Sci., 292 (2014) 1961
  17. Probing mass transfer in mesoporous faujasite-type zeolite nanosheet assemblies
    Mehlhorn, D., A. Inayat, W. Schwieger, R. Valiullin, and J. Kärger, ChemPhysChem, 15 (2014) 1681
  18. Filling dynamics of closed end nanocapillaries
    Schneider, D., R. Valiullin, and P. A. Monson, Langmuir, 30 (2014) 1290
  19. Understanding Adsorption and Transport of Light Gases in Hierarchical Materials Using Molecular Simulation and Effective Medium Theory
    Bonilla, M.R., R. Valiullin, J. Kärger, and S.K. Bhatia, J. Phys. Chem. C, 118 (2014) 14355
  20. Water-Mediated Proton Conduction in a Robust Triazolyl Phosphonate Metal–Organic Framework with Hydrophilic Nanochannels
    Begum, S., Z. Wang, A. Donnadio, F. Costantino, M. Casciola, R. Valiullin, C. Chmelik, M. Bertmer, J. Kärger, J. Haase, and H. Krautscheid, Chemistry – A European Journal, 20 (2014) 8862
  21. Transport enhancement in binderless zeolite X- and A-type molecular sieves revealed by PFG NMR diffusometry
    Mehlhorn, D., R. Valiullin, J. Kärger, K. Schumann, A. Brandt, and B. Unger, Microporous Mesoporous Mat., 188 (2014) 126
  22. Short-time diffusion behavior of Brownian particles in porous solids
    Fatkullin, N. and R. Valiullin, Magnetic Resonance in Solids, 16 (2014) 14202
  23. Diffusion in Nanoporous Host Systems
    Valiullin, R., Annual Reports on NMR Spectroscopy, 79 (2013) 23
  24. Mass transfer in mesoporous materials: The benefit of microscopic diffusion measurement
    Kärger, J. and R. Valiullin, Chem. Soc. Rev., 42 (2013) 4172
  25. Improving structural analysis of disordered mesoporous materials using NMR cryoporometry
    Kondrashova, D. and R. Valiullin, Microporous Mesoporous Mat., 178 (2013) 15
  26. Diffusion in Microporous Materials with Embedded Mesoporosities
    Zeigermann, P., J. Kärger, and R. Valiullin, Microporous Mesoporous Mat., 178 (2013) 84
  27. Shakhov, A., C. Reichenbach, D. Kondrashova, P. Zeigermann, D. Mehlhorn, D. Enke, and R. Valiullin, Chem. Ing. Tech., 85 (2013) 1734
  28. The Mechanism of Pseudomorphic Transformation of Spherical Silica Gel into MCM-41 Studied by PFG NMR Diffusometry
    Einicke, W.-D., D. Enke, M. Dvoyashkin, R. Valiullin, and R. Gläser, Materials, 6 (2013) 3688 
    (open access)
  29. Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA
    Bonilla, M., T. Titze, F. Schmidt, D. Mehlhorn, C. Chmelik, R. Valiullin, S. Bhatia, S. Kaskel, R. Ryoo, and J. Kärger, Materials, 6 (2013) 2662 (open access)
  30. The interplay between inter- and intra-molecular dynamics in a series of alkylcitrates
    Kipnusu, W.K., W. Kossack, C. Iacob, P. Zeigermann, M. Jasiurkowska, J.R. Sangoro, R. Valiullin, and F. Kremer, Soft Matter, 9 (2013) 4681
  31. Die innere Größe macht's
    Kärger, J., C. Chmelik, and R. Valiullin, Physik Journal, 12 (2013) 39 
  32. Transport Properties of Gas-Expanded Liquids in Bulk and under Confinement
    Zeigermann, P. and R. Valiullin, J. Supercrit. Fluid., 75 (2013) 43 
  33. Exploring the hierarchy of transport phenomena in hierarchical pore systems by NMR diffusion measurement
    Mehlhorn, D., R. Valiullin, J. Kärger, K. Cho, and R. Ryoo, Microporous Mesoporous Mat., 164 (2012) 273
  34. Tracing Molecular Propagation in Dextran Solutions by Pulsed Field Gradient NMR
    Shakhov, A., R. Valiullin, and J. Kärger, J. Phys. Chem. Lett., 3 (2012) 1854 
  35. Probing Mesopore Connectivity in Hierarchical Nanoporous Materials
    Kirchner, T., A. Shakhov, P. Zeigermann, R. Valiullin, and J. Kärger, Carbon, 50 (2012) 4084
  36. Diffusion in hierarchical mesoporous materials: Applicability and generalization of the fast-exchange diffusion model
    Zeigermann, P., S. Naumov, S. Mascotto, J. Kärger, B.M. Smarsly, and R. Valiullin, Langmuir, 28 (2012) 3621 
  37. Single-Particle and Ensemble Diffusivities—Test of Ergodicity
    Feil, F., S. Naumov, J. Michaelis, R. Valiullin, D. Enke, J. Kärger, and C. Bräuchle, Angew. Chem., 124 (2012) 1178 
    Highlights: Ergodic theorem passes the test; Feel the pulse: fundamental facts; Glowing beacons reveal hidden order in dynamic systems; Diffusion plays by the rules; Grundlegendes naturwissenschaftliches Prinzip erstmals nachgewiesenAuf dem Prüfstand, Physik Journal; Cover image
  38. Monitoring Molecular Mass Transfer in Cation-Free Nanoporous Host Crystals of Type AlPO-LTA
    Hibbe, F., J. Caro, C. Chmelik, A. Huang, T. Kirchner, D. Ruthven, R. Valiullin, and J. Kärger, J. Am. Chem. Soc., 134 (2012) 7725
  39. Exploring Mass Transfer in Mesoporous Zeolites by NMR Diffusometry
    Mehlhorn, D., R. Valiullin, J. Kärger, K. Cho, and R. Ryoo, Materials, 5 (2012) 699 (open access)
  40. Intracrystalline Diffusion in Mesoporous Zeolites
    Mehlhorn, D., R. Valiullin, J. Kärger, K. Cho, and R. Ryoo, ChemPhysChem, 13 (2012) 1495 
  41. Enhanced charge transport in nano-confined ionic liquids
    Iacob, C., J.R. Sangoro, W.K. Kipnusu, R. Valiullin, J. Kärger, and F. Kremer, Soft Matter, 8 (2012) 289
  42. How to compare diffusion processes assessed by single-particle tracking and pulsed field gradient nuclear magnetic resonance
    Bauer, M., R. Valiullin, G. Radons, and J. Kärger, J. Chem. Phys., 135 (2011) 144118 
  43. How Hydrogen Bonds Influence the Mobility of Imidazolium-Based Ionic Liquids. A Combined Theoretical and Experimental Study of 1-n-Butyl-3-methylimidazolium Bromide
    Kohagen, M., M. Brehm, Y. Lingscheid, R. Giernoth, J. Sangoro, F. Kremer, S. Naumov, C. Iacob, J. Kärger, R. Valiullin, and B. Kirchner, J. Phys. Chem. B, 115 (2011) 15280
  44. Rotational and translational diffusion in glass-forming N,N,-diethyl-3-methylbenzamide (DEET)
    Sangoro, J.R., C. Iacob, W.K. Kipnusu, M. Jasiurkowska, R. Valiullin, C. Friedrich, J. Karger, and F. Kremer, Soft Matter, 7 (2011) 10565
  45. Role of stringlike, supramolecular assemblies in reentrant supernematic liquid crystals
    Mazza, M.G., M. Greschek, R. Valiullin, and M. Schoen, Phys. Rev. E, 83 (2011) 051704
  46. Guest diffusion in interpenetrating networks of micro- and mesopores
    Furtado, F., P. Galvosas, M. Gonçalves, F.-D. Kopinke, S. Naumov, F. Rodríguez-Reinoso, U. Roland, R. Valiullin, and J. Kärger, J. Am. Chem. Soc., 133 (2011) 2437
  47. Structural characterization of porous solids by simultaneously monitoring the low-temperature phase equilibria and diffusion of intrapore fluids using nuclear magnetic resonance
    Kondrashova, D., M. Dvoyashkin, and R. Valiullin, New J. Phys., 13 (2011) 015008 
  48. Dynamics of water diffusion in mesoporous zeolites
    Valiullin, R., J. Kärger, K. Cho, M. Choi, and R. Ryoo, Microporous Mesoporous Mat., 142 (2011) 236
  49. Diffusion in ionic liquids: the interplay between molecular structure and dynamics
    Sangoro,  J.R., C. Iacob, S. Naumov, R. Valiullin, H. Rexhausen, J. Hunger, R.  Buchner, V. Strehmel, J. Kärger, and F. Kremer, Soft Matter, 7 (2011) 1678
  50. The evidence of NMR diffusometry on pore space heterogeneity in activated carbon
    Furtado, F., P. Galvosas, M. Gonçalves, F.D. Kopinke, S. Naumov, F. Rodríguez-Reinoso, U. Roland, R. Valiullin, and J. Kärger, Microporous Mesoporous Mat., 141 (2011) 184
  51. The impact of mesopores on mass transfer in nanoporous materials: evidence of diffusion measurement by NMR
    Valiullin, R. and J. Kärger, Chemie Ingenieur Technik, 83 (2011) 166 
  52. Diffusion of cyclohexane in native and surface-modified mesoporous glasses
    Dvoyashkin, M., E. Romanova, W.D. Einicke, R. Gläser, J. Kärger, and R. Valiullin, Adsorption, 17 (2011) 93 
  53. Phase state and dynamics of fluids in mesoporous solids
    Valiullin, R., AIP Conf. Proc., 1330 (2011) 39 
  54. Diffusion and phase equilibria of binary fluids in mesopores
    Zeigermann, P., M. Dvoyashkin, and R. Valiullin, Adsorption, 17 (2011) 69
  55. Diffusion NMR of fluids confined to mesopores under high pressures
    Zeigermann, P., M. Dvoyashkin, R. Gläser, and R. Valiullin, AIP Conf. Proc., 1330 (2011) 97
  56. Guest Diffusion in Binderless High-Performance NaX Molecular Sieves
    Mehlhorn, D., R. Valiullin, J. Kärger, K. Schumann, A. Brandt, and B. Unger, Chem. Ing. Tech., 83 (2011) 2251
  57. Entropy-driven enhanced self-diffusion in confined reentrant supernematics
    Mazza, M.G., M. Greschek, R. Valiullin, J. Kärger, and M. Schoen, Phys. Rev. Lett., 105 (2010) 227802
  58. Charge transport and diffusion of ionic liquids in nanoporous silica membranes
    Iacob, C., J.R. Sangoro, P. Papadopoulos, T. Schubert, S. Naumov, R. Valiullin, J. Kärger, and F. Kremer, Phys. Chem. Chem. Phys., 12 (2010) 13798
  59. Comment on "Single-file diffusion of confined water inside SWNTs: An NMR study"
    Valiullin, R. and J. Kärger, ACS Nano, 4 (2010) 3537 
  60. A new view of diffusion in nanoporous materials
    Chmelik, C., L. Heinke, and R. Valiullin, and J. Kärger, Chemie Ingenieur Technik, 82 (2010) 779
  61. Comment on “Computer Simulation of Static and Dynamic Properties During Transient Sorption of Fluids in Mesoporous Materials”
    Valiullin, R., S. Naumov, P. Galvosas, J. Kärger, H.J. Woo, F. Porcheron, and P.A. Monson, J. Phys. Chem. C, 114 (2010) 9187
  62. Probing pore connectivity in random porous materials by scanning freezing and melting experiments
    Kondrashova, D., C. Reichenbach, and R. Valiullin, Langmuir, 26 (2010) 6380 
  63. Correlating phase behaviour and diffusion in mesopores: perspectives revealed by pulsed field gradient NMR
    Valiullin, R., J. Kärger, and R. Gläser, Phys. Chem. Chem. Phys., 11 (2009) 2833 
    Highlights: Cover image
  64. Understanding adsorption and desorption processes in mesoporous materials with independent disordered channels
    Naumov, S., R. Valiullin, J. Kärger, and P.A. Monson, Phys. Rev. E, 80 (2009) 031607 
  65. Pulsed field gradient NMR study of surface diffusion in mesoporous adsorbents
    Dvoyashkin, M., A. Khokhlov, S. Naumov, and R. Valiullin, Microporous Mesoporous Mat., 125 (2009) 58 
  66. Normal and anomalous diffusion of non-interacting particles in linear nanopores
    Zschiegner, S., S. Russ, R. Valiullin, M.O. Coppens, A.J. Dammers, A. Bunde, and J. Kärger, Eur. Phys. J. Special Topics, 161 (2008) 109
  67. Probing memory effects in confined fluids via diffusion measurements
    Naumov, S., R. Valiullin, P.A. Monson, and J. Kärger, Langmuir, 24 (2008) 6429 
  68. Tracing pore connectivity and architecture in nanostructured silica SBA-15
    Naumov, S., R. Valiullin, J. Kärger, R. Pitchumani, and M.-O. Coppens, Microporous Mesoporous Mat., 110 (2008) 37 
  69. Understanding capillary condensation and hysteresis in porous silicon: Network effects within independent pores
    Naumov, S., A. Khokhlov, R. Valiullin, J. Kärger, and P.A. Monson, Phys. Rev. E, 78 (2008) 060601 
  70. Characterization of pore size distribution in porous silicon by NMR cryoporosimetry and adsorption methods
    Khokhlov, A.G., R.R. Valiullin, M.A. Stepovich, and J. Kärger, Colloid J., 70 (2008) 507 
  71. Estimation of pore sizes in porous silicon by scanning electron microscopy and NMR cryoporometry
    Khokhlov, A.G., R.R. Valiullin, J. Kärger, N.B. Zubareva, and M.A. Stepovich, J. Surf. Ingestig.-X-Ray Synchro., 2 (2008) 919
  72. Freezing of fluids in disordered mesopores
    Dvoyashkin, M., A. Khokhlov, R. Valiullin, and J. Kärger, J. Chem. Phys., 129 (2008) 154702 
  73. Dynamical aspects of the adsorption hysteresis phenomenon
    Valiullin, R., S. Naumov, P. Galvosas, J. Kärger, and P.A. Monson, Magn. Reson. Imaging, 25 (2007) 481
  74. Diffusion of guest molecules in MCM-41 agglomerates
    Valiullin, R., M. Dvoyashkin, P. Kortunov, C. Krause, and J. Kärger, J. Chem. Phys., 126 (2007) 054705
  75. Diffusion processes in mesoporous adsorbents probed by NMR
    Valiullin, R. and M. Dvoyashkin, Adsorption, 13 (2007) 239
  76. Diffusion hysteresis in mesoporous materials
    Naumov, S., R. Valiullin, P. Galvosas, J. Kärger, and P.A. Monson, Eur. Phys. J. Special Topics, 141 (2007) 107
  77. Freezing and melting transitions of liquids in mesopores with ink-bottle geometry
    Khokhlov, A., R. Valiullin, J. Kärger, F. Steinbach, and A. Feldhoff, New J. Phys., 9 (2007) 27 
  78. Direct assessment of transport properties of supercritical fluids confined to nanopores
    Dvoyashkin, M., R. Valiullin, J. Kärger, W.-D. Einicke, and R. Gläser, J. Am. Chem. Soc., 129 (2007) 10344 
  79. Supercritical fluids in mesopores - new insight using NMR
    Dvoyashkin, M., R. Valiullin, and J. Kärger, Adsorption, 13 (2007) 197
  80. Temperature effects on phase equilibrium and diffusion in mesopores
    Dvoyashkin, M., R. Valiullin, and J. Kärger, Phys. Rev. E, 75 (2007) 041202
  81. Exploration of molecular dynamics during transient sorption of fluids in mesoporous materials
    Valiullin, R., S. Naumov, P. Galvosas, J. Kärger, H.J. Woo, F. Porcheron, and P.A. Monson, Nature, 443 (2006) 965 
    HighlightsPorous materials: How molecules huddle in holes (Nature Physics, 2 (2006) 732)
  82. Orientational ordering of linear n-alkanes in silicon nanotubes
    Valiullin, R. and A. Khokhlov, Phys. Rev. E, 73 (2006) 051605 
  83. Concentration-dependent self-diffusion of adsorbates in mesoporous materials
    Valiullin, R., P. Kortunov, J. Kärger, and V. Timoshenko, Magn. Reson. Imaging, 23 (2005) 209
  84. Surface self-diffusion of organic molecules adsorbed in porous silicon
    Valiullin, R., P. Kortunov, J. Kärger, and V. Timoshenko, J. Phys. Chem. B, 109 (2005) 5746 
  85. The role of mesopores in intracrystalline transport in USY zeolite: PFG NMR diffusion study on various length scales
    Kortunov, P., S. Vasenkov, J. Kärger, R. Valiullin, P. Gottschalk, M.F. Elia, M. Perez, M. Stocker, B. Drescher, G. McElhiney, C. Berger, R. Gläser, and J. Weitkamp, J. Am. Chem. Soc., 127 (2005) 13055
  86. Molecular dynamics under confinement to one-dimension: options of measurement and accessible information
    Kärger, J., R. Valiullin, and S. Vasenkov, New J. Phys., 7 (2005) 15 
  87. Liquid-liquid phase separation in micropores
    Valiullin, R., D. Vargas-Krusa, and I. Furo, Current Applied Physics, 4 (2004) 370 
  88. Concentration-dependent self-diffusion of liquids in nanopores: A nuclear magnetic resonance study
    Valiullin, R., P. Kortunov, J. Kärger, and V. Timoshenko, J. Chem. Phys., 120 (2004) 11804 
  89. Comparison of NMR cryoporometry, mercury intrusion porosimetry, and DSC thermoporosimetry in characterizing pore size distributions of compressed finely ground calcium carbonate structures
    Gane, P.A.C., C.J. Ridgway, E. Lehtinen, R. Valiullin, I. Furo, J. Schoelkopf, H. Paulapuro, and J. Daicic, Ind. Eng. Chem. Res., 43 (2004) 7920 
  90. NMR magnetization transfer as a tool for characterization of nanoporous materials
    Valiullin, R., I. Furo, V. Skirda, and P. Kortunov, Magn. Reson. Imaging, 21 (2003) 299 
  91. Low-temperature phase separation of a binary liquid mixture in porous materials studied by cryoporometry and pulsed-field-gradient NMR
    Valiullin, R. and I. Furo, Phys. Rev. E, 66 (2002) 031508 
  92. Phase separation of a binary liquid mixture in porous media studied by nuclear magnetic resonance cryoporometry
    Valiullin, R. and I. Furo, J. Chem. Phys., 116 (2002) 1072 
  93. The morphology of coexisting liquid and frozen phases in porous materials as revealed by exchange of nuclear spin magnetization followed by H-1 nuclear magnetic resonance
    Valiullin, R. and I. Furo, J. Chem. Phys., 117 (2002) 2307 
  94. Adsorption isotherm and aggregate properties of fluorosurfactants on alumina measured by F-19 NMR
    Evenas, L., I. Furo, P. Stilbs, and R. Valiullin, Langmuir, 18 (2002) 8096
  95. Time dependent self-diffusion coefficient of molecules in porous media
    Valiullin, R. and V. Skirda, J. Chem. Phys., 114 (2001) 452 
  96. Self-diffusion of water and oil in peanuts investigated by PFG NMR
    Zakhartchenko, N.L., V.D. Skirda, and R. Valiullin, Magn. Reson. Imaging, 16 (1998) 583 
  97. Molecular exchange processes in partially filled porous glass as seen with NMR diffusometry
    Valiullin, R., V.D. Skirda, S. Stapf, and R. Kimmich, Phys. Rev. E, 55 (1997) 2664 
  98. Levy walks of strong adsorbates on surfaces: Computer simulation and spin-lattice relaxation
    Valiullin, R., R. Kimmich, and N. Fatkullin, Phys. Rev. E, 56 (1997) 4371 
  99. Peculiarities of self-diffusion of alkane molecules in kaolinite
    Dvoyashkin, N.K., V.D. Skirda, A.I. Maklakov, M.V. Belousova, and R. Valiullin, Appl. Magn. Reson., 2 (1991) 83
 
 
 
 
 
   
© Rustem Valiullin, 2006-2013