Contents
Preface
Chapter 1 The Organic Set of NMR Spectra
1.1 The 1H NMR
Experiment
1.2 APT-13C NMR
1.3 COSY
1.4
NOESY
1.5 HSQC
1.6
HMBC
Chapter 2 Advanced Organic NMR Spectroscopy
2.1 2D J-Resolved 1H NMR
Spectroscopy
2.2 ROESY
2.3 TOCSY
2.4
HSQC-TOCSY
2.5 HOESY
2.6 INADEQUATE
2.7
ADEQUATE
2.8 J-HMBC
2.9 Gated Decoupling
Chapter 3 Selective Methods
3.1 Water suppression by Presaturation
3.2
Solvent Suppression by 1D-NOESY
3.3 Water Suppression by Soggy Excitation Sculpting
3.4 Solvent Suppression using
WET
3.5 SELTOCSY
3.6 SELNOESY
3.7
SELINCOR
3.8 SELINQUATE
3.9 Band Selective HMBC
Chapter 4 Heteronuclear NMR
4.1 11B NMR Spectroscopy
4.2 15N
NMR Spectroscopy
4.3 17O NMR Spectroscopy
4.4 19F NMR
Spectroscopy
4.5 29Si NMR Spectroscopy
4.6 57Fe NMR
Spectroscopy
4.7 195Pt NMR Spectroscopy
Chapter 5 Experiments in Physical Organic Chemistry
5.1 Measurement of the Spin–Lattice Relaxation Time T1
5.2
Measurement of the Spin–Spin Relaxation Time T2
5.3 Dynamic 1H NMR Spectroscopy
5.4
Diffusion Measurement with DOSY
5.5 Residual Dipolar Couplings (RDC)
Chapter 6 Organic Chemistry Applications
6.1 ASIS
6.2 Chirality
Determination
6.3 Advanced Mosher Method
6.4 Quantitative NMR and Relaxation
Reagents
6.5 Determination of Association Constant K
6.6 STD NMR
6.7 A Kinetic
Experiment
Chapter 7 An Excursion to the Solid State and to Structural Biology
7.1 The CP/MAS
Experiment
7.2 High-Resolution Magic-Angle Spinning
7.3 HN-HSQC
7.4 HNCA
Chapter 8 Maintenance and Calibration
8.1 Calibration of Pulse Duration in the Transmitter
Channel
8.2 Calibration of the Pulse Duration in the Indirect Channe
8.3 Shaped
Pulses
8.4 Adiabatic pulses
8.5 Temperature Calibration in NMR
8.6 Calibration
of Pulsed Field Gradients
Appendix
- Answers
- Pulse Programs
- Elementary Product Operator Formalism Rules
- Chemical Shift and Spin-Coupling Data for Strychnine
- Picture Credits
- Index
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